Local structure and dynamics of high temperature SrO-Al2O3 liquids studied by 27Al NMR and SrK-edge XAS spectroscopy

被引：13

作者：

Capron, M

Florian, P

Fayon, F

Trumeau, D

Hennet, L

Gaihlanou, M

Thiaudière, D

Landron, C

Douy, A

Massiot, D

机构：

[1] CNRS, CRMHT, Ctr Rech Mat Haute Temp, F-45071 Orleans 2, France

[2] Univ Paris 11, Lab Utilisat Rayonnement Electromagnet, LURE, F-91405 Orsay, France

来源：

JOURNAL OF NON-CRYSTALLINE SOLIDS | 2001年 / 293卷

关键词：

D O I：

10.1016/S0022-3093(01)00762-1

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

In situ spectroscopic studies of liquid oxides at temperatures greater than 2000 degreesC remain challenging experiments but provide a unique opportunity to better understand their physical properties. Aerodynamic levitation, combined with laser heating, has been conducted with NMR or XAS spectroscopy to obtain the characterisation of local structure and dynamics of very high temperature liquids of the SrO-Al2O3 binary system. We present and discuss results obtained using time resolved Al-27 NMR in the range 1800(.)2300 degreesC for seven different compositions and the first results obtained by Sr K-edge XAS for the SrO-Al2O3 binary system. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：496 / 501

页数：6

共 9 条

[1] Structure of liquid aluminum oxide [J].