Transition state in a noisy environment

被引：79

作者：

Bartsch, T ^{[1
]}

Hernandez, R ^{[1
]}

Uzer, T ^{[1
]}

机构：

[1] Georgia Inst Technol, Ctr Nonlinear Sci, Atlanta, GA 30332 USA

来源：

PHYSICAL REVIEW LETTERS | 2005年 / 95卷 / 05期

关键词：

D O I：

10.1103/PhysRevLett.95.058301

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

Transition state theory overestimates reaction rates in solution because conventional dividing surfaces between reagents and products are crossed many times by the same reactive trajectory. We describe a recipe for constructing a time-dependent dividing surface free of such recrossings in the presence of noise. The no-recrossing limit of transition state theory thus becomes generally available for the description of reactions in a fluctuating environment.

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