Efficient electrocatalytic hydrogen production from H+ ions using specially designed boron-capped cobalt clathrochelates

被引：84

作者：

Voloshin, Yan Z. ^{[1
]}

Dolganov, Alexander V. ^{[1
]}

Varzatskii, Oleg A. ^{[2
]}

Bubnov, Yurii N. ^{[1
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia

[2] Natl Acad Sci Ukraine, Vernadskii Inst Gen & Inorgan Chem, UA-03680 Kiev, Ukraine

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 27期

关键词：

MOLECULAR CATALYSTS; H-2; PRODUCTION; ACTIVE-SITE; IRON; EVOLUTION; COMPLEXES; OXIDATION; MODELS; MIMICS;

D O I：

10.1039/c1cc12239h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Specially designed hexachlorine-containing cobalt(II) tris-dioximate clathrochelates were found to efficiently electrocatalyze the production of molecular hydrogen from H+ ions without the overpotential of this process.

引用

页码：7737 / 7739

页数：3

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