Soft-Templated Mesoporous Carbon-Carbon Nanotube Composites for High Performance Lithium-ion Batteries

被引:370
作者
Guo, Bingkun [1 ]
Wang, Xiqing [1 ]
Fulvio, Pasquale F. [1 ]
Chi, Miaofang [3 ]
Mahurin, Shannon M. [1 ]
Sun, Xiao-Guang [1 ]
Dai, Sheng [1 ,2 ]
机构
[1] Oak Ridge Natl Lab, Div Chem Sci, Oak Ridge, TN 37831 USA
[2] Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA
[3] Oak Ridge Natl Lab, Div Mat Sci & Technol, Oak Ridge, TN 37831 USA
关键词
ADSORPTION CHARACTERIZATION; DISORDERED CARBON; ANODE MATERIAL; STORAGE; CAPACITY; NANOCOMPOSITES; PYROLYSIS; SPHERULES; INSERTION; ELECTRODE;
D O I
10.1002/adma.201102032
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Mesoporous carbon with homogeneously dispersed multi-walled carbon nanotubes (MWNTs) are synthesized via a one-step "brick and mortar" soft-templating approach. Nanocomposites exhibit a reversible lithium storage capacity of 900 mA h g(-1) and a good rate performance. Such homogeneous nanocomposites are ideal candidates for electric vehicle applications where high power and energy density are primary requirements.
引用
收藏
页码:4661 / +
页数:7
相关论文
共 33 条
[1]   A disordered carbon as a novel anode material in lithium-ion cells [J].
Bonino, F ;
Brutti, S ;
Reale, P ;
Scrosati, B ;
Gherghel, L ;
Wu, J ;
Müllen, K .
ADVANCED MATERIALS, 2005, 17 (06) :743-+
[2]   MECHANISMS FOR LITHIUM INSERTION IN CARBONACEOUS MATERIALS [J].
DAHN, JR ;
ZHENG, T ;
LIU, YH ;
XUE, JS .
SCIENCE, 1995, 270 (5236) :590-593
[3]   Recent development of carbon materials for Li ion batteries [J].
Endo, M ;
Kim, C ;
Nishimura, K ;
Fujino, T ;
Miyashita, K .
CARBON, 2000, 38 (02) :183-197
[4]   "Brick-and-Mortar" Self-Assembly Approach to Graphitic Mesoporous Carbon Nanocomposites [J].
Fulvio, Pasquale F. ;
Mayes, Richard T. ;
Wang, Xiqing ;
Mahurin, Shannon M. ;
Bauer, John C. ;
Presser, Volker ;
McDonough, John ;
Gogotsi, Yury ;
Dai, Sheng .
ADVANCED FUNCTIONAL MATERIALS, 2011, 21 (12) :2208-2215
[5]   Influence of micropore structure on Li-storage capacity in hard carbon spherules [J].
Hu, J ;
Li, H ;
Huang, XJ .
SOLID STATE IONICS, 2005, 176 (11-12) :1151-1159
[6]   Synthesis of hierarchically porous carbon monoliths with highly ordered microstructure and their application in rechargeable lithium batteries with high-rate capability [J].
Hu, Yong-Sheng ;
Adelhelm, Philipp ;
Smarsly, Bernd M. ;
Hore, Sarmimala ;
Antonietti, Markus ;
Maier, Joachim .
ADVANCED FUNCTIONAL MATERIALS, 2007, 17 (12) :1873-1878
[7]   Synthesis of new, nanoporous carbon with hexagonally ordered mesostructure [J].
Jun, S ;
Joo, SH ;
Ryoo, R ;
Kruk, M ;
Jaroniec, M ;
Liu, Z ;
Ohsuna, T ;
Terasaki, O .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (43) :10712-10713
[8]   Lithium Storage ion Carbon Nanostructures [J].
Kaskhedikar, Nitin A. ;
Maier, Joachim .
ADVANCED MATERIALS, 2009, 21 (25-26) :2664-2680
[9]   Gas adsorption characterization of ordered organic-inorganic nanocomposite materials [J].
Kruk, M ;
Jaroniec, M .
CHEMISTRY OF MATERIALS, 2001, 13 (10) :3169-3183
[10]   Nitrogen adsorption characterization of aligned multiwalled carbon nanotubes and their acid modification [J].
Li, ZJ ;
Pan, ZW ;
Dai, S .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2004, 277 (01) :35-42