Stable analogs of the uranyl ion containing the -N=U=N- group

被引：45

作者：

Brown, DR ^{[1
]}

Denning, RG ^{[1
]}

机构：

[1] UNIV OXFORD,INORGAN CHEM LAB,OXFORD OX1 3QR,ENGLAND

来源：

INORGANIC CHEMISTRY | 1996年 / 35卷 / 21期

关键词：

D O I：

10.1021/ic951386v

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of compounds containing the -N=U=N- group has been prepared. Their physical and chemical properties are reported. They adopt a trans configuration, and are thermally robust. The chemistry of some recently-prepared O=U=N- compounds is also described. These are the first examples of stable analogs of the uranyl ion UO22+. The factors that determine their stability are discussed.

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页码：6158 / 6163

页数：6

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