Stable analogs of the uranyl ion containing the -N=U=N- group

被引:43
作者
Brown, DR [1 ]
Denning, RG [1 ]
机构
[1] UNIV OXFORD,INORGAN CHEM LAB,OXFORD OX1 3QR,ENGLAND
关键词
D O I
10.1021/ic951386v
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A series of compounds containing the -N=U=N- group has been prepared. Their physical and chemical properties are reported. They adopt a trans configuration, and are thermally robust. The chemistry of some recently-prepared O=U=N- compounds is also described. These are the first examples of stable analogs of the uranyl ion UO22+. The factors that determine their stability are discussed.
引用
收藏
页码:6158 / 6163
页数:6
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