An oxidation of alcohols by oxygen with the enzyme laccase and mediation by TEMPO

被引：187

作者：

Fabbrini, M

Galli, C

Gentili, P

Macchitella, D

机构：

[1] Univ Roma La Sapienza, Dipartimento Chim, I-00185 Rome, Italy

[2] CNR, I-00185 Rome, Italy

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 43期

关键词：

laccase; TEMPO; oxidation; alcohols; mediation;

D O I：

10.1016/S0040-4039(01)01463-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A simple and efficient oxidation of alcohols to carbonyl compounds by oxygen at room temperature is described; it requires the laccase/TEMPO mediator system as the catalyst. A possible mechanistic explanation is provided. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：7551 / 7553

页数：3

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