Magnetic field effect on N-ethylcarbazole-dimethylterephthalate and N-ethylcarbazole-1,4-dicyanobenzene:: A comparitive study focusing on steric effect

被引：5

作者：

Choudhury, SD ^{[1
]}

Basu, S ^{[1
]}

机构：

[1] Saha Inst Nucl Phys, Div Chem Sci, Kolkata 700064, W Bengal, India

来源：

CHEMICAL PHYSICS LETTERS | 2005年 / 408卷 / 4-6期

关键词：

D O I：

10.1016/j.cplett.2005.04.066

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This work is a comparative study of magnetic field effect (MFE) on photoinduced electron transfer between N-ethylcarbazole (ECZ)-dimethylterephthalate (DMT) pair and ECZ-1,4-dicyanobenzene (DCB) pair. Our aim was to see how a change in the steric bulk of the acceptor is manifested in the magnetic field behaviour of a system. The steric effect in DMT is responsible for maximization of MFE at a higher dielectric constant, e; sustaining spin correlation to a larger extent so that the MFE vs. 8 plot is broad and enhancing free ion formation so that the MFE is lower for ECZ-DMT compared to ECZ-DCB. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：274 / 278

页数：5

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