Oxidation mechanism of NAD dimer model compounds

被引：60

作者：

Patz, M ^{[1
]}

Kuwahara, Y ^{[1
]}

Suenobu, T ^{[1
]}

Fukuzumi, S ^{[1
]}

机构：

[1] OSAKA UNIV, FAC ENGN, DEPT APPL CHEM, SUITA, OSAKA 565, JAPAN

来源：

CHEMISTRY LETTERS | 1997年 / 06期

关键词：

D O I：

10.1246/cl.1997.567

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The oxidation of a dimeric N-benzyldihydronicotinamide with various oxidants such as quinones, triphenyl carbenium ions and a triplet exited tris(bipyridine) ruthenium(rr) complex occurs via initial outer-sphere electron transfer followed by fast C-C bond cleavage and second electron transfer. The kinetic studies allow the determination of the oxidation potential of this compound.

引用

页码：567 / 568

页数：2

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