[Ga51(PtBu2)14Br6]3-:: An elementoid gallium cluster with metalloid and nonmetalloid structural elements

被引：26

作者：

Steiner, J ^{[1
]}

Stösser, G ^{[1
]}

Schnöckel, H ^{[1
]}

机构：

[1] Univ Karlsruhe, Inst Anorgan Chem, D-76128 Karlsruhe, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 03期

关键词：

cluster compounds; gallium; structure elucidation;

D O I：

10.1002/anie.200352472

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Metal or nonmetal? Gallium is a chameleon, both as an element and in a metalloid Ga51 cluster. The cluster consists of a central Ga 13, unit with the same fcc topology as the high-pressure form of Ga-IV. A second shell of Ga atoms and GaBr and GaPR2 groups binds the central core in a corset-like molecular structure (see picture).

引用

页码：302 / 305

页数：4

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