High pressure effects on the Raman spectrum of CsC60 polymer

被引：6

作者：

Arvanitidis, J ^{[1
]}

Papagelis, K

Tsilika, I

Kanellis, G

Ves, S

Kourouklis, GA

Tanigaki, K

Prassides, K

机构：

[1] Aristotelian Univ Salonika, Dept Phys, GR-54006 Salonika, Greece

[2] Aristotelian Univ Salonika, Sch Technol, Div Phys, GR-54006 Salonika, Greece

[3] NEC Corp Ltd, Fundamental Res Lab, Tsukuba, Ibaraki 305, Japan

[4] Univ Sussex, Sch Chem Phys & Environm Sci, Brighton BN1 9QJ, E Sussex, England

来源：

PHYSICA B | 1999年 / 265卷 / 1-4期

关键词：

fullerides; polymeric fullerides and fullerite derivatives; CsC60; Raman spectroscopy;

D O I：

10.1016/S0921-4526(98)01382-9

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

The effect of high pressure (up to 11 GPa) on the phonon modes of o-CsC60 polymer has been studied by means of Raman spectroscopy. The pressure dependence of all the observed phonon frequencies exhibits reversible changes in the pressure region 4.3 +/- 0.5 GPa. The width of the H-8(8) mode increases almost linearly with increasing pressure up to similar to 4.3 GPa, above which it seems to remain constant. All the above changes may be related to the metal insulator transition observed below 50 K for the material under investigation and/or with the structural changes, induced by pressure and observed also by X-ray diffraction measurements, (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：234 / 238

页数：5

共 18 条

[1]

Arvanitidis J, 1999, PHYS STATUS SOLIDI B, V211, P435, DOI 10.1002/(SICI)1521-3951(199901)211:1<435::AID-PSSB435>3.0.CO

[2]

2-W

[3]

Barnett D., 1973, REV SCI INSTRUM, V44, P1

[4] Raman study of the polymerized state of RbC60 and CsC60 [J].

Bormann, D ;

Sauvajol, JL ;

Goze, C ;

Rachdi, F ;

Moreac, A ;

Girard, A ;

Forro, L ;

Chauvet, O .

PHYSICAL REVIEW B, 1996, 54 (19) :14139-14145

[5] On the crystal structure of azafullerene (C59N)(2) [J].

Brown, CM ;

Cristofolini, L ;

Kordatos, K ;

Prassides, K ;

Bellavia, C ;

Gonzalez, R ;

KeshavarzK, M ;

Wudl, F ;

Cheetham, AK ;

Zhang, JP ;

Andreoni, W ;

Curioni, A ;

Fitch, AN ;

Pattison, P .

CHEMISTRY OF MATERIALS, 1996, 8 (11) :2548-&

[6] QUASI-ONE-DIMENSIONAL ELECTRONIC-STRUCTURE IN ORTHORHOMBIC RBC60 [J].

CHAUVET, O ;

OSZLANYI, G ;

FORRO, L ;

STEPHENS, PW ;

TEGZE, M ;

FAIGEL, G ;

JANOSSY, A .

PHYSICAL REVIEW LETTERS, 1994, 72 (17) :2721-2724

[7] RELATION OF STRUCTURE AND SUPERCONDUCTING TRANSITION-TEMPERATURES IN A3C60 [J].

FLEMING, RM ;

RAMIREZ, AP ;

ROSSEINSKY, MJ ;

MURPHY, DW ;

HADDON, RC ;

ZAHURAK, SM ;

MAKHIJA, AV .

NATURE, 1991, 352 (6338) :787-788

[8] ULTRAHIGH PRESSURES [J].

JAYARAMAN, A .

REVIEW OF SCIENTIFIC INSTRUMENTS, 1986, 57 (06) :1013-1031

[9] CONDUCTING PHASE OF RAPIDLY COOLED AC(60) (A=CS AND RB) [J].

KOSAKA, M ;

TANIGAKI, K ;

TANAKA, T ;

ATAKE, T ;

LAPPAS, A ;

PRASSIDES, K .

PHYSICAL REVIEW B, 1995, 51 (17) :12018-12021

[10] Polymeric fullerenes [J].

Kuzmany, H ;

Winter, J ;

Burger, B .

SYNTHETIC METALS, 1997, 85 (1-3) :1173-1177

← 1 2 →