Reaction of [60]fullerene with terbium(IV) fluoride

被引：22

作者：

Boltalina, OV ^{[1
]}

Lukonin, AY

Pavlovich, VK

Sidorov, LN

Taylor, R

Abdul-Sada, AK

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119899, Russia

[2] Univ Sussex, Sch CPES, Chem Lab, Brighton BN1 9QJ, E Sussex, England

来源：

FULLERENE SCIENCE AND TECHNOLOGY | 1998年 / 6卷 / 03期

基金：

俄罗斯科学基金会;

关键词：

D O I：

10.1080/10641229809350215

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A reaction between [60]fullerene and terbium(IV) fluoride is shown to be a new example of the thermally induced disruption of the fullerene skeleton. "Hyperfluorination" occurs at the elevated temperature (350 degrees C) thereby producing species C60Fx (x > 60) The fluorination products were characterized by mass spectrometry and IR spectroscopy methods.

引用

页码：469 / 479

页数：11

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