Improved Stability and Smart-Material Functionality Realized in an Energetic Cocrystal

被引：602

作者：

Bolton, Onas ^{[1
,2
]}

Matzger, Adam J. ^{[1
,2
]}

机构：

[1] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA

[2] Univ Michigan, Macromol Engn Program, Ann Arbor, MI 48109 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 38期

关键词：

cocrystallization; crystal growth; explosives; Raman spectroscopy; solid-state structures; CRYSTAL-STRUCTURES; SENSITIVITY; DERIVATIVES; POLYMORPHS; FAMILY;

D O I：

10.1002/anie.201104164

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Handle with care: CL-20, a high-power explosive suffering from high sensitivity, has been cocrystallized with TNT to produce a novel high-power, low-sensitivity explosive. This cocrystal can be used directly for explosives applications or stored in this insensitive form then activated by heat to return it to its high-sensitivity form. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：8960 / 8963

页数：4

共 54 条

[1]

Aakeroy C. B., 2001, ANGEW CHEM, V113, P3340

[2]

Aakeröy CB, 2001, ANGEW CHEM INT EDIT, V40, P3240, DOI 10.1002/1521-3773(20010903)40:17<3240::AID-ANIE3240>3.0.CO

[3]

2-X

[4] Using Cocrystals To Systematically Modulate Aqueous Solubility and Melting Behavior of an Anticancer Drug [J].

Aakeroy, Christer B. ;

Forbes, Safiyyah ;

Desper, John .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (47) :17048-+

[5] Layered porphyrin coordination polymers based on Zinc•••Nitro recognition:: Reversible intercalation of nitrobenzene [J].

Adilov, Salimgerey ;

Thalladi, Venkat R. .

CRYSTAL GROWTH & DESIGN, 2007, 7 (03) :481-484

[6]

[Anonymous], ANGEW CHEM

[7] A systematic experimental and theoretical study of the crystalline state of six chloronitrobenzenes [J].

Barnett, Sarah A. ;

Johnston, Andrea ;

Florence, Alastair J. ;

Price, Sarah L. ;

Tocher, Derek A. .

CRYSTAL GROWTH & DESIGN, 2008, 8 (01) :24-36

[8] Current directions in co-crystal growth [J].

Blagden, Nicholas ;

Berry, David J. ;

Parkin, Andrew ;

Javed, Hafsa ;

Ibrahim, Asim ;

Gavan, Pauline T. ;

De Matos, Luciana L. ;

Seaton, Colin C. .

NEW JOURNAL OF CHEMISTRY, 2008, 32 (10) :1659-1672

[9]

Bolotina NB, 2004, J APPL CRYSTALLOGR, V37, P808, DOI 10.1107/S002188984017832

[10] What is a co-crystal? [J].

Bond, Andrew D. .

CRYSTENGCOMM, 2007, 9 (09) :833-834

← 1 2 3 4 5 6 →