Addition of heterocycles to electron deficient olefins and alkynes catalyzed by gold(III)

被引：124

作者：

Li, ZG ^{[1
]}

Shi, ZJ ^{[1
]}

He, C ^{[1
]}

机构：

[1] Univ Chicago, Dept Chem, Chicago, IL 60637 USA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2005年 / 690卷 / 23期

关键词：

hydroarylation; gold; heterocycle; olefin; C-H functionalization; H BOND ACTIVATION/; GOLD; ARENES; FUNCTIONALIZATION; ALPHA; BETA-ENONES; COMPLEXES; ALKENES; SILVER; MILD;

D O I：

10.1016/j.jorganchem.2005.03.009

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A gold(III)-catalyzed hydroarylation of different olefins is reported here. AuCl3 works as an excellent catalyst to mediate reactions between various heterocycles and electron deficient olefins and alkynes under mild conditions. This gold(III)-based method tolerates different functional groups such as aldehyde, carboxylic acid, nitrile, and is highly efficient. We have shown that some of these reactions complete in minutes at room temperature. (c) 2005 Elsevier B.V. All rights reserved.

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页码：5049 / 5054

页数：6

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