Molecular structure of [CpFe(CO)(2)]2AlAr (Ar=2-[(dimethylamino)methyl]phenyl): An alanediyl complex with two Fe-Al bonds

被引：27

作者：

Braunschweig, H

Muller, J

Ganter, B

机构：

[1] Inst. für Anorganische Chemie, Technische Hochschule Aachen

来源：

INORGANIC CHEMISTRY | 1996年 / 35卷 / 25期

关键词：

D O I：

10.1021/ic960471f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new Fe-Al complexes ArAl[CpFe(CO)(2)]Cl (1) and ArAl[CpFe(CO)(2)](2) (2) (Ar = 2-[(dimethylamino)methyl]phenyl), respectively, were synthesized by the reaction of ArAlCl2 with 1 or 2 equiv of Na[CpFe(CO)(2)]. The structures of these products were deduced from NMR (H-1, C-13, Al-27) and IR measurements and are confirmed by X-ray structural determination of 2.

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页码：7443 / +

页数：3

相关论文

共 11 条

[1] HYDROGEN-ATOM TRANSFER-REACTIONS OF TRANSITION-METAL HYDRIDES - KINETICS AND MECHANISM OF THE HYDROGENATION OF ALPHA-CYCLOPROPYLSTYRENE BY METAL-CARBONYL HYDRIDES [J].

BULLOCK, RM ;

SAMSEL, EG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (19) :6886-6898

[2] COORDINATION OF METAL-CARBONYL ANIONS TO TRIPHENYLALUMINUM, TRIPHENYL-GALLIUM, AND TRIPHENYL-INDIUM AND THE CRYSTAL-STRUCTURE OF TETRAETHYLAMMONIUM TRIPHENYL((ETA-5-CYCLOPENTADIENYL)DICARBONYLIRON)ALUMINATE(FE-AL) [J].

BURLITCH, JM ;

LEONOWICZ, ME ;

PETERSEN, RB ;

HUGHES, RE .

INORGANIC CHEMISTRY, 1979, 18 (04) :1097-1105

[3]

DOHMEIER C, 1994, ANGEW CHEM INT EDIT, V33, P2482

[4] TRANSITION-METAL-SUBSTITUTED ALANES - SYNTHESIS AND SPECTROSCOPIC STUDIES AND THE STRUCTURE OF (ETA(5)-C5H5)(CO)(2)FE-AL[(CH2)(3)NME(2)]((I)BU) [J].

FISCHER, RA ;

PRIERMEIER, T .

ORGANOMETALLICS, 1994, 13 (11) :4306-4314

[5]

HAARLAND A, 1993, COORDINATION CHEM AL, pCH1

[6] GROUP-13 HALIDES AND HYDRIDES WITH O-(AMINOMETHYL)PHENYL SUBSTITUENTS [J].

ISOM, HS ;

COWLEY, AH ;

DECKEN, A ;

SISSINGH, F ;

CORBELIN, S ;

LAGOW, RJ .

ORGANOMETALLICS, 1995, 14 (05) :2400-2406

[7]

*MOLEN, 1990, INT STRUCT SOL PROC

[8] SYNTHESES AND STRUCTURES OF INTRAMOLECULARLY STABILIZED ORGANOALUMINUM COMPOUNDS [J].

MULLER, J ;

ENGLERT, U .

CHEMISCHE BERICHTE, 1995, 128 (05) :493-497

[9] A SEMI-EMPIRICAL METHOD OF ABSORPTION CORRECTION [J].

NORTH, ACT ;

PHILLIPS, DC ;

MATHEWS, FS .

ACTA CRYSTALLOGRAPHICA SECTION A-CRYSTAL PHYSICS DIFFRACTION THEORETICAL AND GENERAL CRYSTALLOGRAPHY, 1968, A 24 :351-&

[10] ALKYL AND ARYL DERIVATIVES OF PI-CYCLOPENTADIENYL COMPOUNDS OF CHROMIUM, MOLYBDENUM, TUNGSTEN, AND IRON [J].

PIPER, TS ;

WILKINSON, G .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1956, 3 (02) :104-124