Sandwiching C70 between two crown ether-bound cations:: regioselective synthesis, electrochemistry and cation binding properties of C70 bis-crown ether conjugates

被引：16

作者：

van Eis, MJ

Núñez, IP

Muslinkina, LA

Alvarado, RJ

Pretsch, E

Echegoyen, L

Diederich, F

机构：

[1] ETH Zentrum, Organ Chem Lab, CH-8092 Zurich, Switzerland

[2] Univ A Coruna, Dept Quim Fundamental, E-15071 La Coruna, Spain

[3] Univ Miami, Dept Chem, Coral Gables, FL 33124 USA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 2001年 / 10期

关键词：

D O I：

10.1039/b106136b

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Tetrakis-adducts of C-70, featuring two covalently attached crown ethers, form stable 1:1 and 1:2 host-guest complexes with alkali metal cations. A large influence of cation complexation on the first reduction potential of the fullerene was observed.

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页码：1890 / 1892

页数：3

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