Single crystal growth and structure refinement of Li4Ti5O12

被引：54

作者：

Kataoka, Kunimitsu ^{[1
,2
]}

Takahashia, Yasuhiko ^{[2
]}

Kijima, Norihito ^{[2
]}

Akimoto, Junji ^{[2
]}

Ohshima, Ken-ichi ^{[1
]}

机构：

[1] Univ Tsukuba, Grad Sch Pure & Appl Sci, Tsukuba, Ibaraki 3058573, Japan

[2] Natl Inst Adv Ind Sci & Technol, Tsukuba, Ibaraki 3058565, Japan

来源：

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS | 2008年 / 69卷 / 5-6期

关键词：

oxides; crystal growth; x-ray diffraction; crystal structure;

D O I：

10.1016/j.jpcs.2007.10.134

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Single crystal of Li4Ti5O12 was synthesized by a flux method using LiCl flux. The obtained Li4Ti5O12 single crystal is colorless and has the shape of a rod. Li4Ti5O12 crystallizes in the cubic spinel type structure, space group Fd (3) over barm, a = 8.352 (4)angstrom, V = 583.6 (8) angstrom(3), and Z = 8. The structure was determined by a single-crystal X-ray study and refined to the conventional values of R 3.6% and wR = 3.3% for 209 independent observed reflections. (c) 2007 Elsevier Ltd. All rights reserved.

引用

页码：1454 / 1456

页数：3

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