Non-sea salt sulfate and other aerosol constituents at the South Pole during ISCAT

被引：41

作者：

Arimoto, R ^{[1
]}

Nottingham, AS

Webb, J

Schloesslin, CA

Davis, DD

机构：

[1] New Mexico State Univ, Carlsbad Environm Monitoring & Res Ctr, Carlsbad, NM 88220 USA

[2] Georgia Inst Technol, Sch Earth & Atmospher Sci, Atlanta, GA 30332 USA

来源：

GEOPHYSICAL RESEARCH LETTERS | 2001年 / 28卷 / 19期

关键词：

D O I：

10.1029/2000GL012714

中图分类号：

P [天文学、地球科学];

学科分类号：

07 ;

摘要：

Bulk aerosol samples collected at the South Pole were analyzed for Na, SO42-, Cl-, NO3-, methanesulfonate (MSA), Pb-210 and Po-210. Sea salt concentrations were relatively high compared with previous reports, with Na, averaging 45 ng m(-3). Chloride was depleted, by similar to 65% compared with its ratio to Na in seawater. Non-sea salt sulfate (NSS) avera, ged 212 ng m-, and less than 5% of the sulfate was from sea salt. The mean concentration of MSA (an indicator of marine biogenic sulfur) was 12 ng m(-3), and the MSA/NSS mass ratio (0.059) was similar to that in Antarctic ice. Although MSA and NSS were correlated, the data set is not sufficiently robust to draw a quantitative conclusion concerning the fraction of NSS that is biogenic. Data for Po-210 and Pb-210 showed no evidence for strong volcanic influences on sulfate, and NSS also was not correlated with NO3-, a possible tracer of continental emissions.

引用

页码：3645 / 3648

页数：4

共 26 条

[1]

Andreae M.O., 1986, ROLE AIR SEA EXCHANG, P331, DOI [DOI 10.1007/978-94-009-4738-2_14, 10.1007/978-94-009-4738-2_14]

[2] VARIATIONS IN THE METHANESULFONATE TO SULFATE MOLAR RATIO IN SUBMICROMETER MARINE AEROSOL-PARTICLES OVER THE SOUTH-PACIFIC OCEAN [J].

BATES, TS ;

CALHOUN, JA ;

QUINN, PK .

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1992, 97 (D9) :9859-9865

[3] AIRBORNE MEASUREMENTS OF DIMETHYLSULFIDE, SULFUR-DIOXIDE, AND AEROSOL IONS OVER THE SOUTHERN-OCEAN SOUTH OF AUSTRALIA [J].

BERRESHEIM, H ;

ANDREAE, MO ;

AYERS, GP ;

GILLETT, RW ;

MERRILL, JT ;

DAVIS, VJ ;

CHAMEIDES, WL .

JOURNAL OF ATMOSPHERIC CHEMISTRY, 1990, 10 (03) :341-370

[4] Measurements of dimethyl sulfide, dimethyl sulfoxide, dimethyl sulfone, and aerosol ions at Palmer Station, Antarctica [J].

Berresheim, H ;

Huey, JW ;

Thorn, RP ;

Eisele, FL ;

Tanner, DJ ;

Jefferson, A .

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1998, 103 (D1) :1629-1637

[5] SULFATE AEROSOL AND CLIMATE [J].

CHARLSON, RJ ;

LANGNER, J ;

RODHE, H .

NATURE, 1990, 348 (6296) :22-22

[6] DMS oxidation in the Antarctic marine boundary layer:: Comparison of model simulations and field observations of DMS, DMSO, DMSO2, H2SO4(g), MSA(g), and MSA(p) [J].

Davis, D ;

Chen, G ;

Kasibhatla, P ;

Jefferson, A ;

Tanner, D ;

Eisele, F ;

Lenschow, D ;

Neff, W ;

Berresheim, H .

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1998, 103 (D1) :1657-1678

[7] Sulfate in air and snow at the South Pole: Implications for transport and deposition at sites with low snow accumulation [J].

Harder, S ;

Warren, SG ;

Charlson, RJ .

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 2000, 105 (D18) :22825-22832

[8] Sources and sinks of H2SO4 in the remote Antarctic marine boundary layer [J].

Jefferson, A ;

Tanner, DJ ;

Eisele, FL ;

Berresheim, H .

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1998, 103 (D1) :1639-1645

[9] Composite global emissions of reactive chlorine from anthropogenic and natural sources: Reactive Chlorine Emissions Inventory [J].

Keene, WC ;

Khalil, MAK ;

Erickson, DJ ;

McCulloch, A ;

Graedel, TE ;

Lobert, JM ;

Aucott, ML ;

Gong, SL ;

Harper, DB ;

Kleiman, G ;

Midgley, P ;

Moore, RM ;

Seuzaret, C ;

Sturges, WT ;

Benkovitz, CM ;

Koropalov, V ;

Barrie, LA ;

Li, YF .

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1999, 104 (D7) :8429-8440

[10] ICE-CORE RECORD OF OCEANIC EMISSIONS OF DIMETHYLSULFIDE DURING THE LAST CLIMATE CYCLE [J].

LEGRAND, M ;

FENIETSAIGNE, C ;

SALTZMAN, ES ;

GERMAIN, C ;

BARKOV, NI ;

PETROV, VN .

NATURE, 1991, 350 (6314) :144-146

← 1 2 3 →