A facile one-pot construction of supramolecular polymer micelles from α-cyclodextrin and poly(ε-caprolactone)

被引：59

作者：

Dong, Haiqing ^{[1
,2
]}

Li, Yongyong ^{[1
,2
]}

Cai, Shaojun ^{[1
,2
]}

Zhuo, Renxi ^{[1
,2
]}

Zhang, Xianzheng ^{[1
,2
]}

Liu, Lijian ^{[1
,2
]}

机构：

[1] Wuhan Univ, Key Lab Biomed Polymers Minist Educ, Wuhan 430072, Peoples R China

[2] Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 30期

关键词：

cyclodextrins; host-guest chemistry; micelles; poly(epsilon-caprolactone); supramolecular chemistry;

D O I：

10.1002/anie.200800952

中图分类号：

O6 [化学];

学科分类号：

0703 [化学];

摘要：

(Figure Presented) A matter of control: A method has been developed for the construction of supramolecular polymer micelles (SMPMs) from α-cyclodextrin (α-CD) and poly(ε-caprolactone) (PCL) by controlling the intermolecular hydrogen bonds between CDs (see scheme). These micelles show great potential for use as drug carriers, templates for the synthesis of inorganic nanoparticles, and nanoreactors. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

收藏

页码：5573 / 5576

页数：4

相关论文

共 13 条

[1]

Hydrogen-bond-induced inclusion complex in aqueous cellulose/LiOH/urea solution at low temperature [J].

Cai, Jie ;

Zhang, Lina ;

Chang, Chunyu ;

Cheng, Gongzhen ;

Chen, Xuming ;

Chu, Benjamin .

CHEMPHYSCHEM, 2007, 8 (10) :1572-1579

[2]

DOU H, 2003, ANGEW CHEM, V115, P1554

[3]

pH-dependent self-assembly: Micellization and micelle-hollow-sphere transition of cellulose-based copolymers [J].

Dou, HJ ;

Jiang, M ;

Peng, HS ;

Chen, DY ;

Hong, Y .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (13) :1516-1519

[4]

PREPARATION AND CHARACTERIZATION OF INCLUSION COMPLEXES OF POLY(PROPYLENE GLYCOL) WITH CYCLODEXTRINS [J].

HARADA, A ;

OKADA, M ;

LI, J ;

KAMACHI, M .

MACROMOLECULES, 1995, 28 (24) :8406-8411

[5]

Cyclodextrin-based supramolecular polymers [J].

Harada, Akira ;

Hashidzume, Akihito ;

Takashima, Yoshinori .

SUPRAMOLECULAR POLYMERS POLYMERIC BETAINS OLIGOMERS, 2006, 201 (1-43) :1-43

[6]

Self-threading and dethreading dynamics of poly(ethylene glycol)-substituted cyclodextrins with different chain lengths [J].

Inoue, Youhei ;

Miyauchi, Masahiko ;

Nakajima, Hiroki ;

Takashima, Yoshinori ;

Yamaguchi, Hiroyasu ;

Harada, Akira .

MACROMOLECULES, 2007, 40 (09) :3256-3262

[7]

Complex formation of poly(ε-caprolactone) with cyclodextrins [J].

Kawaguchi, Y ;

Nishiyama, T ;

Okada, M ;

Kamachi, M ;

Harada, A .

MACROMOLECULES, 2000, 33 (12) :4472-4477

[8]

Formation and characterization of the inclusion compounds between poly(ε-caprolactone)-poly(ethylene oxide)-poly(ε-caprolactone) triblock copolymer and α- and γ-cyclodextrin [J].

Lu, J ;

Shin, ID ;

Nojima, S ;

Tonelli, AE .

POLYMER, 2000, 41 (15) :5871-5883

[9]

Formation process of cyclodextrin necklace - Analysis of hydrogen bonding on a molecular level [J].

Miyake, K ;

Yasuda, S ;

Harada, A ;

Sumaoka, J ;

Komiyama, M ;

Shigekawa, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (17) :5080-5085

[10]

Competitive formation of polymer-cyclodextrin inclusion compounds [J].

Rusa, CC ;

Fox, J ;

Tonelli, AE .

MACROMOLECULES, 2003, 36 (08) :2742-2747