Transforming surface coordination polymers into covalent surface polymers:: Linked polycondensed aromatics through oligomerization of N-heterocyclic carbene intermediates

被引：175

作者：

Matena, Manfred ^{[1
,2
]}

Riehm, Till ^{[4
]}

Stoehr, Meike ^{[1
,2
]}

Jung, Thomas A. ^{[3
]}

Gade, Lutz H. ^{[4
]}

机构：

[1] Univ Basel, NCCR Nanoscale Sci, CH-4056 Basel, Switzerland

[2] Univ Basel, Inst Phys, CH-4056 Basel, Switzerland

[3] Paul Scherrer Inst, Lab Micro & Nanostruct, CH-5232 Villigen, Switzerland

[4] Heidelberg Univ, Inst Anorgan Chem, D-69120 Heidelberg, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 13期

关键词：

N-heterocyclic carbenes; polycyclic aromatic hydrocarbons; scanning probe microscopy; surface chemistry;

D O I：

10.1002/anie.200704072

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Isomerize and polymerize! Thermally induced tautomerization of the N-heteropolycyclic 1,3,8,10-tetraazaperopyrene to a Wanzlick-type carbene intermediate on a Cu(111) surface leads to covalently linked polyaromatic chains, which can be mechanically manipulated. The pictures show the respective structures superimposed on the STM images. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2414 / 2417

页数：4

共 57 条

[1] Submolecular visualisation of palladium acetate complexation with a bipyridine derivative at a graphite surface [J].

Abdel-Mottaleb, MMS ;

Schuurmans, N ;

De Feyter, S ;

Van Esch, J ;

Feringa, BL ;

De Schryver, FC .

CHEMICAL COMMUNICATIONS, 2002, (17) :1894-1895

[2] Iridium(III)-induced isomerization of 2-substituted pyridines to N-heterocyclic carbenes [J].

Alvarez, Eleuterio ;

Conejero, Salvador ;

Paneque, Margarita ;

Petronilho, Ana ;

Poveda, Manuel L. ;

Serrano, Oracio ;

Carmona, Ernesto .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (40) :13060-13061

[3]

[Anonymous], ANGEW CHEM

[4]

[Anonymous], 2005, ANGEW CHEM

[5]

Arduengo AJ, 1998, ANGEW CHEM INT EDIT, V37, P1963, DOI 10.1002/(SICI)1521-3773(19980803)37:13/14<1963::AID-ANIE1963>3.0.CO

[6]

2-M

[7]

Arduengo III A. J., 1998, ANGEW CHEM, V110, P2062

[8] The mechanism of decarboxylation Part II The production of cyanide-like ions from alpha-picolinic, quinaldinic, and isoquinaldinac acids [J].

Ashworth, MRF ;

Daffern, RP ;

Hammick, DL .

JOURNAL OF THE CHEMICAL SOCIETY, 1939, :809-812

[9] MANIPULATION OF C-60 MOLECULES ON A SI SURFACE [J].

BETON, PH ;

DUNN, AW ;

MORIARTY, P .

APPLIED PHYSICS LETTERS, 1995, 67 (08) :1075-1077

[10] Templated growth of metal-organic coordination chains at surfaces [J].

Classen, T ;

Fratesi, G ;

Costantini, G ;

Fabris, S ;

Stadler, FL ;

Kim, C ;

de Gironcoli, S ;

Baroni, S ;

Kern, K .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (38) :6142-6145

← 1 2 3 4 5 6 →