Evidence that the availability of an allylic hydrogen governs the regioselectivity of the Wacker oxidation

被引：22

作者：

Gaunt, MJ ^{[1
]}

Yu, JQ ^{[1
]}

Spencer, JB ^{[1
]}

机构：

[1] Univ Cambridge, Chem Lab, Cambridge CB2 1EW, England

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 18期

关键词：

D O I：

10.1039/b103066n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The allylic hydrogen is found to have a dramatic effect on the regioselectivity of the Wacker oxidation, leading to the postulation that an agostic hydrogen or enyl (sigma+pi) complex helps to stabilise the key intermediate.

引用

页码：1844 / 1845

页数：2

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