N-Heterocyclic Carbene Mediated Activation of Tetravalent Silicon Compounds: A Critical Evaluation

被引：64

作者：

Fuchter, Matthew J. ^{[1
]}

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AZ, England

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2010年 / 16卷 / 41期

基金：

美国国家科学基金会;

关键词：

carbenes; Lewis bases; organocatalysis; polymers; silanes; GROUP-TRANSFER POLYMERIZATION; RING-OPENING POLYMERIZATION; CARBONYL-COMPOUNDS; TRANSESTERIFICATION REACTIONS; HYDROSILYLATION REACTIONS; CATALYTIC-ACTIVITY; LEWIS PAIR; COMPLEXES; ALDEHYDES; CYANOSILYLATION;

D O I：

10.1002/chem.201001120

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An overview of the recent bibliography concerning the N-heterocyclic carbene (NHC)-mediated activation of tetravalent silicon compounds is presented. Diverse reactions are discussed, such as the NHC-mediated addition of silyl pronucleophiles to a variety of electrophiles, NHC-promoted organic and inorganic polymerisation and the reduction of CO2 by hydrosilanes as facilitated by NHCs. The review concludes with a discussion of the current knowledge regarding the role of Lewis acid-base NHC-Si interactions in the mechanistic course of these reactions.

引用

页码：12286 / 12294

页数：9

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