Proton conducting polyaniline molecular sieve composites

被引:24
作者
Coutinho, D
Yang, ZW
Ferraris, JP [1 ]
Balkus, KJ
机构
[1] Univ Texas, Dept Chem, Richardson, TX 75083 USA
[2] Univ Texas, UTD NanoTech Inst, Richardson, TX 75083 USA
关键词
mesoporous molecular sieves; organosilanes; functionalized silica; polyaniline;
D O I
10.1016/j.micromeso.2005.02.014
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Mesoporous SBA-15/polyaniline composites were synthesized and their physical properties were investigated. The polyaniline was polymerized inside the pores of the mesoporous material by a post-synthesis process as well as an in one step process during the preparation of the molecular sieve. These materials were characterized by X-ray diffraction, scanning electron microscopy and nitrogen adsorption. The composite polyaniline/SBA-15 was electrically insulating (dc conductivity similar to 10(-8) S/cm) and produced proton conductivities of up to 10(-2) S/cm when doped with HCl. (c) 2005 Elsevier Inc. All rights reserved.
引用
收藏
页码:321 / 332
页数:12
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