Polynuclear coordination compounds of alkali metal ions with organic chromophores

被引:5
作者
Centore, R [1 ]
Tuzi, A [1 ]
机构
[1] Univ Naples Federico II, Dipartimento Chim, I-80126 Naples, Italy
来源
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2001年 / 57卷
关键词
D O I
10.1107/S0108270101004231
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The crystal structures of sodium 4-({4-[N,N-bis(2-hydroxyethyl)amino]phenyl}diazenyl)benzoate 3.5-hydrate, Na+.-C17H18N3O4-.3.5H(2)O, (I), and potassium 4-({4-[N,N-bis(2-hydroxyethyl)amino]phenyl}diazenyl)benzoate dihydrate, K+.C17H18N3O4-. 2H(2)O, (II), are described. The results indicate an octahedral coordination around sodium in (I) and a trigonal prismatic coordination around potassium in (II). In both cases, coordination around the metal cation is achieved through O atoms of the water molecules and hydroxy groups of the chromophore. The organic conjugated part of the chromophore is approximately planar in (I), while a dihedral angle of 30.7 (2)degrees between the planes of the phenyl rings is observed in (II).
引用
收藏
页码:698 / 701
页数:4
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