Device Characteristics of Bulk-Heterojunction Polymer Solar Cells are Independent of Interfacial Segregation of Active Layers

被引：71

作者：

Wang, He ^{[1
,2
]}

Gomez, Enrique D. ^{[1
]}

Kim, Jongbok ^{[1
]}

Guan, Zelei ^{[2
]}

Jaye, Cherno ^{[3
]}

Fischer, Daniel A. ^{[3
]}

Kahn, Antoine ^{[2
]}

Loo, Yueh-Lin ^{[1
]}

机构：

[1] Princeton Univ, Dept Chem & Biol Engn, Princeton, NJ 08544 USA

[2] Princeton Univ, Dept Elect Engn, Princeton, NJ 08544 USA

[3] NIST, Mat Sci & Engn Lab, Gaithersburg, MD 20899 USA

来源：

CHEMISTRY OF MATERIALS | 2011年 / 23卷 / 08期

基金：

美国国家科学基金会;

关键词：

polymer solar cells; interfacial segregation; delamination; vertical phase separation; GALLIUM-ARSENIDE; PHASE-SEPARATION; TERPHENYLDITHIOL; ORGANIZATION; LAMINATION; BLENDS; SOFT;

D O I：

10.1021/cm200320u

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The ability to reverse the composition profile of active layers by delaminating and transferring P3HT:PCBM thin films has allowed us to probe directly the sole influence of interfacial segregation on solar cell device characteristics on the same device platform. © 2011 American Chemical Society.

引用

页码：2020 / 2023

页数：4

共 21 条

[1] Morphology evolution via self-organization and lateral and vertical diffusion in polymer: fullerene solar cell blends [J].

Campoy-Quiles, Mariano ;

Ferenczi, Toby ;

Agostinelli, Tiziano ;

Etchegoin, Pablo G. ;

Kim, Youngkyoo ;

Anthopoulos, Thomas D. ;

Stavrinou, Paul N. ;

Bradley, Donal D. C. ;

Nelson, Jenny .

NATURE MATERIALS, 2008, 7 (02) :158-164

[2] Wetting at polymer surfaces and interfaces [J].

Geoghegan, M ;

Krausch, G .

PROGRESS IN POLYMER SCIENCE, 2003, 28 (02) :261-302

[3] Interfacial Segregation in Polymer/Fullerene Blend Films for Photovoltaic Devices [J].

Germack, David S. ;

Chan, Calvin K. ;

Kline, R. Joseph ;

Fischer, Daniel A. ;

Gundlach, David J. ;

Toney, Michael F. ;

Richter, Lee J. ;

DeLongchamp, Dean M. .

MACROMOLECULES, 2010, 43 (08) :3828-3836

[4] Substrate-dependent interface composition and charge transport in films for organic photovoltaics [J].

Germack, David S. ;

Chan, Calvin K. ;

Hamadani, Behrang H. ;

Richter, Lee J. ;

Fischer, Daniel A. ;

Gundlach, David J. ;

DeLongchamp, Dean M. .

APPLIED PHYSICS LETTERS, 2009, 94 (23)

[5] Multicomponent semiconducting polymer systems with low crystallization-induced percolation threshold [J].

Goffri, Shalom ;

Mueller, Christian ;

Stingelin-Stutzmann, Natalie ;

Breiby, Dag W. ;

Radano, Christopher P. ;

Andreasen, Jens W. ;

Thompson, Richard ;

Janssen, Rene A. J. ;

Nielsen, Martin M. ;

Smith, Paul ;

Sirringhaus, Henning .

NATURE MATERIALS, 2006, 5 (12) :950-956

[6] Engineering the organic semiconductor-electrode interface in polymer solar cells [J].

Gomez, Enrique D. ;

Loo, Yueh-Lin .

JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (32) :6604-6611

[7] Direct determination of the electronic structure of the poly(3-hexylthiophene):phenyl-[6,6]-C61 butyric acid methyl ester blend [J].

Guan, Ze-Lei ;

Kim, Jong Bok ;

Wang, He ;

Jaye, Cherno ;

Fischer, Daniel A. ;

Loo, Yueh-Lin ;

Kahn, Antoine .

ORGANIC ELECTRONICS, 2010, 11 (11) :1779-1785

[8] Interfacial modification to improve inverted polymer solar cells [J].

Hau, Steven K. ;

Yip, Hin-Lap ;

Acton, Orb ;

Baek, Nam Seob ;

Ma, Hong ;

Jen, Alex K. -Y. .

JOURNAL OF MATERIALS CHEMISTRY, 2008, 18 (42) :5113-5119

[9] Altering the Thermodynamics of Phase Separation in Inverted Bulk-Heterojunction Organic Solar Cells [J].

Kim, Chang Su ;

Tinker, Leonard L. ;

DiSalle, Brian F. ;

Gomez, Enrique D. ;

Lee, Stephanie ;

Bernhard, Stefan ;

Loo, Yueh-Lin .

ADVANCED MATERIALS, 2009, 21 (30) :3110-+

[10] Small-Molecule Thiophene-C60 Dyads As Compatibilizers in Inverted Polymer Solar Cells [J].

Kim, Jong Bok ;

Allen, Kathryn ;

Oh, Soong Ju ;

Lee, Stephanie ;

Toney, Michael F. ;

Kim, Youn Sang ;

Kagan, Cherie R. ;

Nuckolls, Colin ;

Loo, Yueh-Lin .

CHEMISTRY OF MATERIALS, 2010, 22 (20) :5762-5773

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