Ferrocenylborane-amine and monomeric diferrocenylborane: Novel organometallic hydroborating reagents

被引:45
作者
Scheibitz, M
Bats, JW
Bolte, M
Lerner, HW
Wagner, M
机构
[1] Univ Frankfurt, Inst Anorgan Chem, D-60439 Frankfurt, Germany
[2] Univ Frankfurt, Inst Organ Chem, D-60439 Frankfurt, Germany
关键词
D O I
10.1021/om034353t
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The ferrocenylboranes FcBH(2).NMe2Et and Fc(2)BH have been synthesized and characterized by X-ray crystallography, which revealed Fc(2)BH to be monomeric in the solid state. Both compounds undergo hydroboration reactions upon addition of alkynes.
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收藏
页码:940 / 942
页数:3
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