Superparamagnetic high-magnetization microspheres with an Fe3O4@SiO2 core and perpendicularly aligned mesoporous SiO2 shell for removal of microcystins
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Deng, Yonghui
[1
,2
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Qi, Dawei
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Fudan Univ, Shanghai Key Lab Mol Catalysis, Dept Chem, Shanghai 200433, Peoples R China
Fudan Univ, Adv Mat Lab, Shanghai 200433, Peoples R ChinaFudan Univ, Shanghai Key Lab Mol Catalysis, Dept Chem, Shanghai 200433, Peoples R China
Qi, Dawei
[1
,2
]
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Deng, Chunhui
[1
,2
]
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Zhang, Xiangmin
[1
,2
]
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Zhao, Dongyuan
[1
,2
]
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[1] Fudan Univ, Shanghai Key Lab Mol Catalysis, Dept Chem, Shanghai 200433, Peoples R China
[2] Fudan Univ, Adv Mat Lab, Shanghai 200433, Peoples R China
Superparamagnetic microspheres with an Fe3O4@SiO2 core and a perpendiculary aligned mesoporous SiO2 shell were synthesized through a surfactant-templating solgel approach. The microspheres possess high magnetization (53.3 emu/g), high surface area (365 m(2)/g), large pore volume (0.29 cm(3)/g), and uniform mesopore (2.3 nm). By using the unique core-shell microspheres with accessible large pores and excellent magnetic property, a fast removal of microcystins with high efficiency (> 95%) can be achieved.
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