Large solar plant photocatalytic water decontamination: Effect of operational parameters

被引:84
作者
Minero, C [1 ]
Pelizzetti, E [1 ]
Malato, S [1 ]
Blanco, J [1 ]
机构
[1] CIEMAT, PLATAFORMA SOLAR ALMERIA, TABERNAS 04200, ALMERIA, SPAIN
关键词
D O I
10.1016/0038-092X(96)00029-1
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
The effect of the concentration of the photocatalyst, the organic substrate and the light intensity is presented for the photocatalytic degradation of pentachlorophenol in the large solar plant built at the Plataforma Solar de Almeria. The degradation of pentachlorophenol is easily achieved in short residence times. The main factors affecting the total efficiency are discussed in view of a simple model for the primary events in the photocatalytic system. The derived approximated equations are able to fit the experimental data well. The optimization of the degradation and mineralization rates is strongly dependent on the organic substrate and predominantly depends on kinetic factors. The partition or competition of the substrate and its degradation products on the surface of the photocatalyst seems unimportant. Copyright (C) 1996 Elsevier Science Ltd.
引用
收藏
页码:421 / 428
页数:8
相关论文
共 27 条
[1]   SEMICONDUCTOR-SENSITIZED PHOTODEGRADATION OF 4-CHLOROPHENOL IN WATER [J].
ALSAYYED, G ;
DOLIVEIRA, JC ;
PICHAT, P .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 1991, 58 (01) :99-114
[2]  
BAHNEMANN DW, 1993, TR MET ENV, V3, P301
[3]   PHOTODEGRADATION OF PENTACHLOROPHENOL CATALYZED BY SEMICONDUCTOR PARTICLES [J].
BARBENI, M ;
PRAMAURO, E ;
PELIZZETTI, E ;
BORGARELLO, E ;
SERPONE, N .
CHEMOSPHERE, 1985, 14 (02) :195-208
[4]  
CROSBY DG, 1980, ENV CHEM PENTACHLORO
[5]   SENSITIZED PHOTO-OXIDATIONS OF DISSOLVED ALCOHOLS IN HOMOGENEOUS AND HETEROGENEOUS SYSTEMS .2. TIO2-SENSITIZED PHOTODEHYDROGENATIONS OF BENZYL ALCOHOL [J].
CUNNINGHAM, J ;
SRIJARANAI, S .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 1991, 58 (03) :361-371
[6]   FACTORS INFLUENCING EFFICIENCIES OF TIO2-SENSITIZED PHOTODEGRADATION .1. SUBSTITUTED BENZOIC-ACIDS - DISCREPANCIES WITH DARK-ADSORPTION PARAMETERS [J].
CUNNINGHAM, J ;
ALSAYYED, G .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1990, 86 (23) :3935-3941
[7]   A KINETIC-MODEL DESCRIBING PHOTOCATALYTIC OXIDATION USING ILLUMINATED SEMICONDUCTORS [J].
DAVIS, AP ;
HUANG, CP .
CHEMOSPHERE, 1993, 26 (06) :1119-1135
[8]   THE ROLE OF OXYGEN IN PHOTOOXIDATION OF ORGANIC-MOLECULES ON SEMICONDUCTOR PARTICLES [J].
GERISCHER, H ;
HELLER, A .
JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (13) :5261-5267
[9]   PHOTOCATALYTIC DEGRADATION OF ORGANOCHLORINE COMPOUNDS IN SUSPENDED TIO2 [J].
HISANAGA, T ;
HARADA, K ;
TANAKA, K .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 1990, 54 (01) :113-118
[10]   PULSE RADIOLYTIC INVESTIGATIONS OF SOME PEROXYHYDROXYCYCLOHEXADIENYL RADICALS [J].
MICIC, OI ;
NENADOVIC, MT .
JOURNAL OF PHYSICAL CHEMISTRY, 1976, 80 (09) :940-944