Cyclopalladation of thio-substituted benzylideneanilines and their spectral characterization

被引：29

作者：

Basuli, F ^{[1
]}

Chattopadhyay, P ^{[1
]}

Sinha, C ^{[1
]}

机构：

[1] UNIV BURDWAN GOLAPBAG, DEPT CHEM, BURDWAN 713104, W BENGAL, INDIA

来源：

POLYHEDRON | 1996年 / 15卷 / 14期

关键词：

D O I：

10.1016/0277-5387(95)00504-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Several 2-(alkylthio)-N-(benzylidene)anilines [XC(6) H4CH=N C6H4 (2-SR), R = -CH3 (1), -CH(2)Ph (2); X = H(a), 4-CH3 (b), 4-(OCH3) (c), 4-Cl (d) and 4-NO2 (e)] have been synthesized and reacted with Pd(OAc)(2) in boiling benzene. The cyclopalladated acetato complexes (4/5) thus obtained react with LiCl, giving the chloro complexes with the coordination sphere Pd (C, N, S) Cl (6/7). The mode of ligand binding is established with the help of high-resolution H-1 NMR and IR data. Copyright (C) 1996 Elsevier Science Ltd.

引用

页码：2439 / 2444

页数：6

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