Immobilized metal ion-containing ionic liquids: preparation, structure and catalytic performance in Kharasch addition reaction

被引：122

作者：

Sasaki, T ^{[1
]}

Zhong, CM

Tada, M

Iwasawa, Y

机构：

[1] Univ Tokyo, Grad Sch Sci, Dept Chem, Bunkyo Ku, Tokyo 113, Japan

[2] Univ Tokyo, Grad Sch Frontier Sci, Dept Complex Sci & Engn, Kashiwa, Chiba 2778561, Japan

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 19期

关键词：

D O I：

10.1039/b500349k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Immobilized metal ion-containing ionic liquid catalysts were prepared by the reaction between silyl-functionalized imidazolium ionic molecules and surface silanol groups of silica, followed by addition of MnCl2, FeCl2, CoCl2, NiCl2, CuCl2, or PdCl2; only the immobilized copper catalyst, which has a sandwiched CuCl42- moiety, was very active for the Kharasch reaction between styrene and CCl4.

引用

页码：2506 / 2508

页数：3

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