VLE measurements of binary mixtures of methanol, ethanol, 2-methoxy-2-methylpropane, and 2-methoxy-2-methylbutane at 101.32 kPa

被引：53

作者：

Arce, A

MartinezAgeitos, J

Soto, A

机构：

[1] Department of Chemical Engineering, University of Santiago de Compostela

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 1996年 / 41卷 / 04期

关键词：

D O I：

10.1021/je950323o

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Isobaric vapor-liquid equilibrium data for 2-methoxy-2-methylpropane + methanol, 2-methoxy-2-methylpropane + ethanol, methanol + 2-methoxy-2-methylbutane, ethanol + 2-methoxy-2-methylbutane, and 2-methoxy-2-methylpropane + 2-methoxy-2-methylbutane were determined at 101.32 kPa. Fredenslund et al.'s test confirmed the results to be thermodynamically consistent. The VLE data were satisfactorily correlated using the Wilson, NRTL, and UNIQUAC equations for liquid phase activity coefficients and adequately predicted using the ASOG, UNIFAC, UNIFAC-Dortmund, and UNIFAC-Lyngby group contribution methods.

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页码：718 / 723

页数：6

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