Nanocrystal self-assemblies: Fabrication and collective properties

被引:640
作者
Pileni, MP [1 ]
机构
[1] Univ Paris 06, ESA CNRS 7070, Lab LM2N, F-75252 Paris 05, France
关键词
D O I
10.1021/jp0039520
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this feature article, the methods of obtaining various mesostructures made of nanocrystals are described. With silver and silver sulfide, the nanocrystals are able to self organize in 2D and 3D super lattices to form "supra" crystals. With cobalt and ferrites nanocrystals, it has been possible to make ribbons, dots, or labyrinths. These mesostructures present new physical properties differing from those of the isolated nanocrystal and from those of the bulk phase. Collective optical, magnetic, and transport properties are demonstrated. By applying a magnetic field during the deposition process of nanocrystals, the easy axes of the particles are oriented along the direction of the applied field, inducing again the collective magnetic properties.
引用
收藏
页码:3358 / 3371
页数:14
相关论文
共 84 条
[1]   Optical absorption spectra of nanocrystal gold molecules [J].
Alvarez, MM ;
Khoury, JT ;
Schaaff, TG ;
Shafigullin, MN ;
Vezmar, I ;
Whetten, RL .
JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (19) :3706-3712
[2]   Structure and dynamics in alkanethiolate monolayers self-assembled on gold nanoparticles: A DSC, FT-IR, and deuterium NMR study [J].
Badia, A ;
Cuccia, L ;
Demers, L ;
Morin, F ;
Lennox, RB .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (11) :2682-2692
[3]   FORMATION OF MONOLAYER FILMS BY THE SPONTANEOUS ASSEMBLY OF ORGANIC THIOLS FROM SOLUTION ONTO GOLD [J].
BAIN, CD ;
TROUGHTON, EB ;
TAO, YT ;
EVALL, J ;
WHITESIDES, GM ;
NUZZO, RG .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (01) :321-335
[4]   THE POLARIZABILITY OF A SPHEROIDAL PARTICLE ON A SUBSTRATE [J].
BOBBERT, PA ;
VLIEGER, J .
PHYSICA A-STATISTICAL MECHANICS AND ITS APPLICATIONS, 1987, 147 (1-2) :115-141
[5]  
Bohren C. F., 1998, ABSORPTION SCATTERIN
[6]   Controlled growth of gold nanoparticles during ligand exchange [J].
Brown, LO ;
Hutchison, JE .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (04) :882-883
[7]   NOVEL GOLD-DITHIOL NANO-NETWORKS WITH NONMETALLIC ELECTRONIC-PROPERTIES [J].
BRUST, M ;
BETHELL, D ;
SCHIFFRIN, DJ ;
KIELY, CJ .
ADVANCED MATERIALS, 1995, 7 (09) :795-&
[8]   THE OPTICAL-PROPERTIES OF SILVER MICROCRYSTALLITES IN DEPENDENCE ON SIZE AND THE INFLUENCE OF THE MATRIX ENVIRONMENT [J].
CHARLE, KP ;
FRANK, F ;
SCHULZE, W .
BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1984, 88 (04) :350-354
[9]  
CHIKAZUMI S, 1964, PHYSICS MAGNETISM, P283
[10]   Fabrication and alignment of wires in two dimensions [J].
Chung, SW ;
Markovich, G ;
Heath, JR .
JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (35) :6685-6687