Synthesis and characterisation of novel ruthenium(II) bipyridyl and ferrocenoyl cavitand receptors for the recognition of anionic guests

被引:29
作者
Dumazet, I [1 ]
Beer, PD [1 ]
机构
[1] Univ Oxford, Inorgan Chem Lab, Oxford OX1 3QR, England
关键词
onion binding; cavitands; molecular recognition;
D O I
10.1016/S0040-4039(98)02412-5
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Novel ruthenium(II) bipyridyl and ferrocenoyl resorcinarene cavitand receptors have been prepared. The ruthenium(II) bipyridyl modified resorcinarene 4 has been shown by UV visible absorption and fluorescence emission spectroscopy to bind chloride, acetate and benzoate anions with a preference for carboxylate anions. (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:785 / 788
页数:4
相关论文
共 12 条
[1]   Luminescent and redox-active polynuclear transition metal complexes [J].
Balzani, V ;
Juris, A ;
Venturi, M ;
Campagna, S ;
Serroni, S .
CHEMICAL REVIEWS, 1996, 96 (02) :759-833
[2]   Anion selective recognition and optical/electrochemical sensing by novel transition-metal receptor systems [J].
Beer, PD .
CHEMICAL COMMUNICATIONS, 1996, (06) :689-696
[3]   Transition-metal receptor systems for the selective recognition and sensing of anionic guest species [J].
Beer, PD .
ACCOUNTS OF CHEMICAL RESEARCH, 1998, 31 (02) :71-80
[4]   Neutral ferrocenoyl receptors for the selective recognition and sensing of anionic guests [J].
Beer, PD ;
Graydon, AR ;
Johnson, AOM ;
Smith, DK .
INORGANIC CHEMISTRY, 1997, 36 (10) :2112-2118
[5]   Anion selective recognition and sensing by novel macrocyclic transition metal receptor systems. H-1 NMR, electrochemical, and photophysical investigations [J].
Beer, PD ;
Szemes, F ;
Balzani, V ;
Sala, CM ;
Drew, MGB ;
Dent, SW ;
Maestri, M .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (49) :11864-11875
[6]   (Thio)urea resorcinarene cavitands. Complexation and membrane transport of halide anions [J].
Boerrigter, H ;
Grave, L ;
Nissink, JWM ;
Chrisstoffels, LAJ ;
van der Maas, JH ;
Verboom, W ;
de Jong, F ;
Reinhoudt, DN .
JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (13) :4174-4180
[7]   Novel resorcinarene cavitand-based CMP(O) cation ligands: Synthesis and extraction properties [J].
Boerrigter, H ;
Verboom, W ;
Reinhoudt, DN .
JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (21) :7148-7155
[8]   EQNMR - A COMPUTER-PROGRAM FOR THE CALCULATION OF STABILITY-CONSTANTS FROM NUCLEAR-MAGNETIC-RESONANCE CHEMICAL-SHIFT DATA [J].
HYNES, MJ .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (02) :311-312
[9]   CHLOROSULFONYLATED CALIX[4]ARENES - PRECURSORS FOR NEUTRAL ANION RECEPTORS WITH A SELECTIVITY FOR HYDROGEN SULFATE [J].
MORZHERIN, Y ;
RUDKEVICH, DM ;
VERBOOM, W ;
REINHOUDT, DN .
JOURNAL OF ORGANIC CHEMISTRY, 1993, 58 (26) :7602-7605
[10]  
SCHMIDTCHEN FP, 1995, CHEM REV, P1609