Electroreduction of nitrate ion on Pt, Ir and on 70:30 Pt:Ir alloy

被引:66
作者
UretaZanartu, S
Yanez, C
机构
[1] Depto. de Ciencias Químicas, Fac. de Quim. y Biología, Universidad de Santiago de Chile, Santiago 33
关键词
D O I
10.1016/S0013-4686(96)00372-6
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The electro-reduction of nitrate ions in acid medium on Pt, Ir and on a 70:30 Pt, Ir alloy was studied by cyclic voltammetry. The alloy has a higher activity than the pure metals, which was interpreted as being due to bifunctional catalysis. Values for activation energies evaluated from the experimental data and Arrhenius plot are discussed. (C) Elsevier Science Ltd.
引用
收藏
页码:1725 / 1731
页数:7
相关论文
共 28 条
[1]   ANION SURFACE INTERACTIONS .2. NITROUS-OXIDE REDUCTION AS A PROBE OF ANION ADSORPTION ON TRANSITION-METAL SURFACES [J].
AHMADI, A ;
BRACEY, E ;
EVANS, RW ;
ATTARD, G .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1993, 350 (1-2) :297-316
[2]  
[Anonymous], Z PHYS CHEM LEIPZIG
[3]   INSITU STUDIES OF ADSORPTION OF ORGANIC-COMPOUNDS ON PLATINUM-ELECTRODES [J].
BOCKRIS, JOM ;
JENG, KT .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1992, 330 (1-2) :541-581
[4]   ABOUT THE RELATIVE HYDRODESULFURIZATION ACTIVITY OF CO-MO/GAMMA-AL2O3 AND NI-MO/GAMMA-AL2O3 CATALYSTS [J].
BOUYSSIERES, L ;
FLORES, C ;
POBLETE, J ;
LLAMBIAS, FJG .
APPLIED CATALYSIS, 1986, 23 (02) :271-280
[5]   A VOLTAMMETRIC INVESTIGATION OF THE CHARGE STORAGE REACTIONS OF HYDROUS IRIDIUM OXIDE LAYERS [J].
BURKE, LD ;
WHELAN, DP .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1984, 162 (1-2) :121-141
[6]   KINETICS AND MECHANISM OF ELECTROCHEMICAL REDUCTION OF NO2+ IN CONCENTRATED SULFURIC-ACID [J].
CALANDRA, AJ ;
ARVIA, AJ ;
TAMAYO, C ;
HERRERA, J .
ELECTROCHIMICA ACTA, 1972, 17 (11) :2035-&
[7]  
CONWAY BE, 1984, MODERN ASPECTS ELECT, V16, pCH2
[8]   ELECTROLYTICALLY CO-DEPOSITED PLATINUM PALLADIUM ELECTRODES AND THEIR ELECTROCATALYTIC ACTIVITY FOR ETHYLENE-GLYCOL OXIDATION - A SYNERGISTIC EFFECT [J].
DALBAY, N ;
KADIRGAN, F .
ELECTROCHIMICA ACTA, 1991, 36 (02) :353-356
[9]   THE REDUCTION OF NITROUS-OXIDE ON PLATINUM-ELECTRODES IN ACID-SOLUTION [J].
EBERT, H ;
PARSONS, R ;
RITZOULIS, G ;
VANDERNOOT, T .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1989, 264 (1-2) :181-193
[10]   LEAD DEPOSITION AND NITRIC-ACID REDUCTION ON PT (100) AND PT (111) ELECTRODES IN PERCHLORIC-ACID SOLUTIONS [J].
ELOMAR, F ;
DURAND, R .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1984, 178 (02) :343-350