Combinatorial electrochemical synthesis and screening of mesoporous ZnO for photocatalysis

被引：93

作者：

Jaramillo, TF ^{[1
]}

Baeck, SH ^{[1
]}

Kleiman-Shwarsctein, A ^{[1
]}

McFarland, EW ^{[1
]}

机构：

[1] Univ Calif Santa Barbara, Dept Chem Engn, Santa Barbara, CA 93106 USA

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2004年 / 25卷 / 01期

关键词：

combinatorial chemistry; electrochemistry; mesoporous; photochemistry; zinc oxide;

D O I：

10.1002/marc.200300187

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Automated electrochemical synthesis was used to create combinatorial libraries of mesoporous materials using tri-block copolymers as structure directing agents (SDA). An example library of 56 ZnO samples was synthesized, varying concentrations (0-15 wt.-%) of poly(ethylene oxide)-block-poly(propylene oxide)-block-poly(ethylene oxide) - EO20 PO70EO20. High-throughput photoelectrochemical screening for the measurement of water-splitting photocatalysis identified peak performance at 3 wt.-% of the SDA. Lamellar structures and disordered mesopores were observed by TEM and XRD.

引用

页码：297 / 301

页数：5

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