Structure-reactivity study of mechanically activated zinc ferrite

被引：78

作者：

Tkacova, K ^{[1
]}

Sepelak, V ^{[1
]}

Stevulova, N ^{[1
]}

Boldyrev, VV ^{[1
]}

机构：

[1] RUSSIAN ACAD SCI,INST SOLID STATE CHEM,NOVOSIBIRSK,RUSSIA

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 1996年 / 123卷 / 01期

关键词：

D O I：

10.1006/jssc.1996.0157

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Changes in the structure and reactivity of zinc ferrite as a result of mechanical activation and thermal relaxation have been studied. The transition of zinc ferrite into a metastable state is the result of the mechanically induced inversion and the partial deformation of the anion sublattice. The inversion is reversible and the stresses around the deformed bonds may relax during heating, Chemical changes serve as one possible channel of the relaxation. The deformation in octahedral geometry has been hypothetically connected to promotion of the Zn dissolution in diluted acids. A conception on the reason of high-temperature reactivity of mechanically activated zinc ferrite was suggested. (C) 1996 Academic Press, Inc.

引用

页码：100 / 108

页数：9

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