Exceptional coupling of tetrachloroperylene bisimide: Combination of ullmann reaction and C-H transformation

被引：117

作者：

Qian, Hualei

Wang, Zhaohui ^{[1
]}

Yue, Wan

Zhu, Daoben

机构：

[1] Chinese Acad Sci, Inst Chem, Key Lab Organ Solids, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing 100080, Peoples R China

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2007年 / 129卷 / 35期

关键词：

D O I：

10.1021/ja0740972

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We present the facile one-pot synthesis of novel triply linked diperylene bisimide (diPBI) and tetrachlorinated diperylene bisimide (4CldiPBI) by L-proline promoted CuI-involved coupling of tetrachloro-PBI, which represents the first step toward the completely bayregion fused oligo-PBIs. The triply linked fused diPBIs display the broad absorption with high extinction coefficients in the region of visible light and the extremely strong electron-accepting ability, which is very promising for use as functional components of photovoltaic devices.

引用

页码：10664 / +

页数：3

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