The influence of iron chloride addition to the precursor pitch on the formation of activated carbon fibers

被引:14
作者
Alcaniz-Monge, Juan [1 ]
Lillo-Rodenas, M. Angeles [1 ]
Bueno-Lopez, Agustin [1 ]
Illan-Gomez, M. Jose [1 ]
机构
[1] Univ Alicante, Dept Inorgan Chem, E-03080 Alicante, Spain
关键词
activated carbon fiber; catalytic gasification; microporosity and supermicroporosity; mesoporosity;
D O I
10.1016/j.micromeso.2006.10.043
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The addition of a suitable metal compound to the precursor pitch before the preparation of carbon fibers is a promising way for obtaining activated carbon fibers with defined porosity and preparing carbon-supported metal catalysts. The introduction of only 0.1 wt.% of FeCl3 modifies not only the textural properties of the carbon fibers, but also their activation behaviour. The metal addition leads to activated carbon fibers with porosities that differ from those obtained using the pristine precursor. The method is interesting for the preparation of activated carbon fiber-supported iron compounds because it is easy and produces dispersed particles. (c) 2006 Elsevier Inc. All rights reserved.
引用
收藏
页码:202 / 209
页数:8
相关论文
共 50 条
[1]   Methane storage in activated carbon fibres [J].
AlcanizMonge, J ;
delaCasaLillo, MA ;
CazorlaAmoros, D ;
LinaresSolano, A .
CARBON, 1997, 35 (02) :291-297
[2]   EFFECT OF THE ACTIVATING GAS ON TENSILE-STRENGTH AND PORE STRUCTURE OF PITCH-BASED CARBON-FIBERS [J].
ALCANIZMONGE, J ;
CAZORLAAMOROS, D ;
LINARESSOLANO, A ;
YOSHIDA, S ;
OYA, A .
CARBON, 1994, 32 (07) :1277-1283
[3]  
Alvim-Ferraz M. C. M., 1989, FUEL, V68, P635
[4]  
[Anonymous], 1966, Chemistry and Physics of Carbon
[5]  
Baker R.T.K., 1986, NATO ASI SERIES E, P231
[6]   A COMPARISON OF THE CATALYTIC INFLUENCE OF NICKEL, IRON AND NICKEL IRON ON THE GASIFICATION OF GRAPHITE IN VARIOUS GASEOUS ENVIRONMENTS [J].
BAKER, RTK ;
CHLUDZINSKI, JJ ;
SHERWOOD, RD .
CARBON, 1985, 23 (03) :245-254
[7]   On a theory of the van der Waals adsorption of gases [J].
Brunauer, S ;
Deming, LS ;
Deming, WE ;
Teller, E .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1940, 62 :1723-1732
[8]   EVOLUTION OF MICROPORE STRUCTURE OF ACTIVATED-CHARCOAL CLOTH [J].
CARROTT, PJM ;
FREEMAN, JJ .
CARBON, 1991, 29 (4-5) :499-506
[9]   Selective porosity development by calcium-catalyzed carbon gasification [J].
CazorlaAmoros, D ;
RibesPerez, D ;
RomanMartinez, MC ;
LinaresSolano, A .
CARBON, 1996, 34 (07) :869-878
[10]   Removal of volatile organic compound by activated carbon fiber [J].
Das, D ;
Gaur, V ;
Verma, N .
CARBON, 2004, 42 (14) :2949-2962