Electrophoretic deposition - mechanisms, myths and materials

被引:187
作者
Fukada, Y [1 ]
Nagarajan, N [1 ]
Mekky, W [1 ]
Bao, Y [1 ]
Kim, HS [1 ]
Nicholson, PS [1 ]
机构
[1] McMaster Univ, Dept Mat Sci & Engn, Ceram Engn Res Grp, Hamilton, ON L8S 4L7, Canada
关键词
D O I
10.1023/B:JMSC.0000012906.70457.df
中图分类号
T [工业技术];
学科分类号
08 [工学];
摘要
Explanations of the deposition process during electrophoretic deposition (EPD) are presented and their boundary conditions discussed. It is suggested increasing resistance during EPD is due to the deposit and not dilution of current carrying species in the suspension. Dialysis membrane experiments demonstrate ions carry significant current. Side-effects of two suspension-conditioning agents are described, i.e., TMAH and PEI. The former can induce "aging" in suspension as its surface adsorption varies with time and reduces suspension pH. PEI appears to adsorb on all ceramic and metal powders, so may be a universal EPD agent for stoichiometric deposition of ceramic/ceramic and ceramic/metal powder-mixtures. Novel structures produced by EPD are presented. (C) 2004 Kluwer Academic Publishers.
引用
收藏
页码:787 / 801
页数:15
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