Water oxidation catalyzed by a dinuclear Mn complex: A functional model for the oxygen-evolving center of photosystem II

被引：186

作者：

Poulsen, AK

Rompel, A

McKenzie, CJ

机构：

[1] Univ So Denmark, Dept Chem, DK-5230 Odense, Denmark

[2] Univ So Denmark, Dept Biochem & Mol Biol, DK-5230 Odense, Denmark

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 42期

关键词：

bioinorganic chemistry; manganese; N; O ligands; oxidation; photosynthesis;

D O I：

10.1002/anie.200502114

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) A highly specific and catalytic oxidation of water occurs when using a dinuclear Mn complex of a mononegative carboxylate-containing pentadentate ligand (see scheme). Isotope-labeling experiments coupled with membrane inlet mass spectrometry show that one oxygen atom in the evolved O2 molecule is derived from water and the other from the oxidant. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

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页码：6916 / 6920

页数：5

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