Diaquabis(1,10-phenanthroline-κ2N, N′) zinc(II) pentafluorooxoniobate(V)

被引：7

作者：

Zhu, G ^{[1
]}

Liu, YY ^{[1
]}

Wang, G ^{[1
]}

Tang, ZX ^{[1
]}

机构：

[1] NW Univ Xian, Dept Chem, Shaanxi Key Lab PhysicoInorgan Chem, Xian 710069, Shaanxi, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2005年 / 61卷

关键词：

D O I：

10.1107/S1600536805020854

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The crystal structure of the title compound, [Zn(C12H8N2)(2)(H2O)(2)][NbF5O], consists of Zn-II complex cations and Nb-V complex anions. The Zn-II and Nb-V atoms each have a distorted octahedral coordination geometry. The Nb-F bond in the trans position with respect to the Nb=O bond is significantly longer than the other four Nb-F bonds in the same [NbOF5](2-) anion.

引用

页码：M1566 / M1567

页数：2

共 9 条

[1]

*BRUK AXS INC, 2002, SAINT SMART

[2] Composition space of the (CuO, 1/2Nb(2)O(5))/(HF)(x)center dot pyridine/H2O system. Structure and synthesis of [pyH(+)](2)[CuNb2(py)(4)O2F10](2-) and CuNb(py)(4)OF5 [J].