From Vegetable Oils to Polyurethanes: Synthetic Routes to Polyols and Main Industrial Products

被引：415

作者：

Desroches, Myriam ^{[1
]}

Escouvois, Maxime ^{[1
]}

Auvergne, Remi ^{[1
]}

Caillol, Sylvain ^{[1
]}

Boutevin, Bernard ^{[1
]}

机构：

[1] Inst Charles Gerhardt Montpellier, Equipe IAM, CNRS UM2 ENSCM UM1, UMR 5253, F-34296 Montpellier 5, France

来源：

POLYMER REVIEWS | 2012年 / 52卷 / 01期

关键词：

vegetable oils; biobased polyols; polyurethanes; epoxidized vegetable oils; commercial polyols; oxidation; CONJUGATED LINOLEIC-ACID; EPOXIDIZED SOYBEAN OIL; FREE-RADICAL ADDITION; RIGID URETHANE FOAMS; LUBRICANT BASE STOCK; FATTY-ACIDS; RENEWABLE RESOURCES; PHYSICAL-PROPERTIES; METHYL OLEATE; LINSEED OIL;

D O I：

10.1080/15583724.2011.640443

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Most of biobased polyols for polyurethanes are synthesized from vegetable oils. In the first part, the present review goes into details of these different synthetic routes to obtain polyols. First, olefinic functionalities of triglycerides could easily be epoxidized, leading to reactive epoxide groups. Second, triglycerides double bonds could undergo a wide ranges of reactions to yield polyols. Finally, the carbonyl group could also be used as a reactive group to yield various polyols. In the second part, the present review is dedicated to the commercial biobased polyols, and, based on the patent literature focuses on the industrial synthetic routes.

引用

页码：38 / 79

页数：42

共 210 条

[1] Polynonanolactone Synthesized from Vegetable Oil: Evaluation of Physical Properties, Biodegradation, and Drug Release Behavior [J].