Nanoscale heterogeneity of glass-forming liquids: experimental advances

被引:83
作者
Bohmer, R [1 ]
机构
[1] Johannes Gutenberg Univ Mainz, Inst Phys Chem, D-55099 Mainz, Germany
关键词
D O I
10.1016/S1359-0286(98)80048-X
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Recent evidence indicates that in supercooled liquids the cooperativity of molecular motion extends over certain temporal and spatial ranges. A key advance is the experimental and theoretical exploration of higher-order correlation functions that can track the molecular coordinates for more than just two points in time or space. Uncontested experimental determinations of the heterogeneity length scale at the glass transition remain a major goal.
引用
收藏
页码:378 / 385
页数:8
相关论文
共 65 条
  • [1] alpha-Relaxation in the glass-transition range of amorphous polymers .2. Influence of physical aging on the dielectric relaxation
    Alegria, A
    Goitiandia, L
    Telleria, I
    Colmenero, J
    [J]. MACROMOLECULES, 1997, 30 (13) : 3881 - 3887
  • [2] Evidence of a fractional Debye-Stokes-Einstein law in supercooled o-terphenyl
    Andreozzi, L
    DiSchino, A
    Giordano, M
    Leporini, D
    [J]. EUROPHYSICS LETTERS, 1997, 38 (09): : 669 - 674
  • [3] Length scale of cooperativity in the dynamic glass transition
    Arndt, M
    Stannarius, R
    Groothues, H
    Hempel, E
    Kremer, F
    [J]. PHYSICAL REVIEW LETTERS, 1997, 79 (11) : 2077 - 2080
  • [4] USE OF STRUCTURAL PROBE IONS FOR RELAXATION STUDIES IN GLASSES .1. SPECTROSCOPIC PROPERTIES OF COBALT(II) IN CHLORIDE-DOPED POTASSIUM NITRATE CALCIUM NITRATE GLASSES
    BARKATT, A
    ANGELL, CA
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1975, 79 (20) : 2192 - 2197
  • [5] Glass transition in liquids: Two versus three-dimensional confinement
    Barut, G
    Pissis, P
    Pelster, R
    Nimtz, G
    [J]. PHYSICAL REVIEW LETTERS, 1998, 80 (16) : 3543 - 3546
  • [6] BOHMER R, 1994, DISORDER EFFECTS ON RELAXATIONAL PROCESSES, P11
  • [7] Böhmer R, 1998, J CHEM PHYS, V108, P890, DOI 10.1063/1.475452
  • [8] Nature of the non-exponential primary relaxation in structural glass-formers probed by dynamically selective experiments
    Bohmer, R
    Chamberlin, RV
    Diezemann, G
    Geil, B
    Heuer, A
    Hinze, G
    Kuebler, SC
    Richert, R
    Schiener, B
    Sillescu, H
    Spiess, HW
    Tracht, U
    Wilhelm, M
    [J]. JOURNAL OF NON-CRYSTALLINE SOLIDS, 1998, 235 : 1 - 9
  • [9] BOHMER R, 1992, J PHYS CHEM-US, V96, P9089, DOI 10.1021/j100202a001
  • [10] BOHMER R, 1998, IN PRESS PHASE T, V65