Palladium-catalyzed thiocarbonylation of iodoarenes with thiols in phosphonium salt ionic liquids

被引：125

作者：

Cao, Hong ^{[1
]}

McNamee, Laura ^{[1
]}

Alper, Howard ^{[1
]}

机构：

[1] Univ Ottawa, Dept Chem, Ctr Catalysis Res & Innovat, Ottawa, ON K1N 6N5, Canada

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2008年 / 73卷 / 09期

关键词：

D O I：

10.1021/jo800287s

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Trihexyl(tetradecyl)phosphonium hexafluorophosphate, a phosphonium salt ionic liquid (PSIL) is a particularly effective general reaction media for the Pd-catalyzed carbonylation reaction of iodoarenes and thiols to form thioesters. Recycling of the ionic liquid containing active Pd-catalyst was also demonstrated.

引用

页码：3530 / 3534

页数：5

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