Novel Quinoxaline-Based Organic Sensitizers for Dye-Sensitized Solar Cells

被引:173
作者
Chang, Dong Wook [1 ]
Lee, Hyo Joong [2 ]
Kim, Jong H. [3 ,4 ]
Park, Soo Young [3 ,4 ]
Park, Su-Moon [1 ]
Dai, Liming [1 ,5 ]
Baek, Jong-Beom [1 ]
机构
[1] Ulsan Natl Inst Sci & Technol, Interdisciplinary Sch Green Energy, Inst Adv Mat & Devices, Ulsan 689798, South Korea
[2] Chonbuk Natl Univ, Dept Chem, Jeonju 561756, South Korea
[3] Seoul Natl Univ, Creat Res Initiat, Ctr Supramol Optoelect Mat, Seoul 151742, South Korea
[4] Seoul Natl Univ, WCU Hybrid Mat Program, Dept Mat Sci & Engn, Seoul 151742, South Korea
[5] Case Western Reserve Univ, Dept Macromol Sci & Engn, Cleveland, OH 44106 USA
关键词
NANOCRYSTALLINE TIO2; FUSED PORPHYRINS; DONOR; EFFICIENCY; ELECTRON;
D O I
10.1021/ol2012378
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Novel quinoxaline-based organic sensitizers using vertical (RC-21) and horizontal (RC-22) conjugation between an electron-donating triphenylamine unit and electron-accepting quinoxaline unit have been synthesized and used for dye-sensitized solar cells (DSSCs), leading to the relatively high power conversion efficiencies of 3.30 and 5.56% for RC-21 and RC-22, respectively. This result indicates that the quinoxaline electron-accepting unit is quite a promising candidate In organic sensitizers.
引用
收藏
页码:3880 / 3883
页数:4
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