Methanol synthesis from CO2 over Cu/ZnO catalysts prepared from various coprecipitated precursors

被引:59
作者
Fujita, S [1 ]
Kanamori, Y [1 ]
Satriyo, AM [1 ]
Takezawa, N [1 ]
机构
[1] Hokkaido Univ, Grad Sch Engn, Div Engn & Mat Sci, Sapporo, Hokkaido 060, Japan
关键词
methanol synthesis; hydrogenation of CO2; coprecipitation; aurichalcite; malachite;
D O I
10.1016/S0920-5861(98)00222-3
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Various precursors of Cu/ZnO catalysts were prepared by coprecipitation methods. By varying the conditions of coprecipitation, precursors having different structures (aurichalcite, malachite, hydrozincite, or their mixture) were obtained at given Cu/Zn ratios, ranging from 30/70 to 70/30. In a wide range of the Cu/Zn ratios, the catalysts derived from the precursors containing aurichalcite exhibited high performance in the methanol synthesis from CO2. (C) 1998 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:241 / 244
页数:4
相关论文
共 12 条
[1]  
Bart J. C., 1987, CATAL TODAY, V2, P1
[2]   Mechanisms of methanol synthesis from carbon dioxide and from carbon monoxide at atmospheric pressure over Cu/ZnO [J].
Fujita, S ;
Usui, M ;
Ito, H ;
Takezawa, N .
JOURNAL OF CATALYSIS, 1995, 157 (02) :403-413
[3]   METHANOL SYNTHESIS FROM CARBON-DIOXIDE AT ATMOSPHERIC-PRESSURE OVER CU/ZNO CATALYST - ROLE OF METHOXIDE SPECIES FORMED ON ZNO SUPPORT [J].
FUJITA, S ;
USUI, M ;
OHARA, E ;
TAKEZAWA, N .
CATALYSIS LETTERS, 1992, 13 (04) :349-358
[4]   TEMPERATURE-PROGRAMMED OXIDATION OF CU/ZNO CATALYSTS WITH N2O - AN ATTEMPT FOR CHARACTERIZATION OF COPPER-CATALYSTS [J].
FUJITA, S ;
MATSUMOTO, S ;
TAKEZAWA, N .
CATALYSIS LETTERS, 1994, 25 (1-2) :29-36
[5]   Migration and reduction of formate to form methanol on Cu/ZnO catalysts [J].
Joo, OS ;
Jung, KD ;
Han, SH ;
Uhm, SJ ;
Lee, DK ;
Ihm, SK .
APPLIED CATALYSIS A-GENERAL, 1996, 135 (02) :273-286
[6]   Characterization of precursors of methanol synthesis catalysts, copper zinc aluminum oxides, precipitated at different pHs and temperatures [J].
Li, JL ;
Inui, T .
APPLIED CATALYSIS A-GENERAL, 1996, 137 (01) :105-117
[7]   A COMBINED TEMPERATURE-PROGRAMMED REACTION SPECTROSCOPY AND FOURIER-TRANSFORM INFRARED-SPECTROSCOPY STUDY OF CO2-H2 AND CO-CO2-H2 INTERACTIONS WITH MODEL ZNO/SIO2, CU/SIO2 AND CU/ZNO/SIO2 METHANOL-SYNTHESIS CATALYSTS [J].
MILLAR, GJ ;
ROCHESTER, CH ;
BAILEY, S ;
WAUGH, KC .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1992, 88 (14) :2085-2093
[8]  
Nakamura J, 1996, STUD SURF SCI CATAL, V101, P1389
[9]   The role of ZnO in Cu/ZnO methanol synthesis catalysts [J].
Nakamura, J ;
Uchijima, T ;
Kanai, Y ;
Fujitani, T .
CATALYSIS TODAY, 1996, 28 (03) :223-230
[10]   STRUCTURAL CHARACTERIZATION OF MALACHITE-LIKE COPRECIPITATED PRECURSORS OF BINARY CUO-ZNO CATALYSTS [J].
PORTA, P ;
DEROSSI, S ;
FERRARIS, G ;
LOJACONO, M ;
MINELLI, G ;
MORETTI, G .
JOURNAL OF CATALYSIS, 1988, 109 (02) :367-377