Gas-phase tropospheric chemistry of biogenic volatile organic compounds: a review

被引：1017

作者：

Atkinson, R

Arey, J ^{[1
]}

机构：

[1] Univ Calif Riverside, Air Pollut Res Ctr, Fawcett Lab 201, Riverside, CA 92521 USA

[2] Univ Calif Riverside, Dept Environm Sci, Riverside, CA 92521 USA

[3] Univ Calif Riverside, Grad Program Environm Toxicol, Riverside, CA 92521 USA

来源：

ATMOSPHERIC ENVIRONMENT | 2003年 / 37卷

关键词：

biogenic volatile organic compound; atmospheric chemistry; hydroxyl radical; nitrate radical; ozone; reaction products;

D O I：

10.1016/S1352-2310(03)00391-1

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Large quantities of non-methane organic compounds are emitted into the atmosphere from biogenic sources, mainly from vegetation. These organic compounds include isoprene, C10H16 monoterpenes, C15H24 sesquiterpenes, and a number of oxygenated compounds including methanol, hexene derivatives, 2-methyl-3-buten-2-ol, and 6-methyl-5-hepten-2-one. In the troposphere these organic compounds react with hydroxyl (OH) radicals, nitrate (NO3) radicals and ozone (O-3), and play an important role in the chemistry of the lower troposphere. In this article the kinetics, products and mechanisms of the tropospheric reactions of biogenic organic compounds are presented and briefly discussed. (C) 2003 Elsevier Ltd. All rights reserved.

引用

页码：S197 / S219

页数：23

共 160 条

[1] Products of the gas-phase reactions of O(3P) atoms and O3 with α-pinene and 1,2-dimethyl-1-cyclohexene [J].