Optical thermometer based on the stability of a phosphorescent 6-bromo-2-naphthol/α-cyclodextrin2 ternary complex

被引:31
作者
Brewster, RE [1 ]
Kidd, MJ [1 ]
Schuh, MD [1 ]
机构
[1] Davidson Coll, Dept Chem, Davidson, NC 28036 USA
关键词
D O I
10.1039/b102156g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The phosphorescence lifetime of a water-soluble ternary complex of 6-bromo-2-naphthol and alpha -cyclodextrin has been found to decrease by more than two orders of magnitude over a 58 degrees temperature range, which makes this molecular system well suited for use as the first optical thermometer based solely on phosphorescence lifetimes.
引用
收藏
页码:1134 / 1135
页数:2
相关论文
共 22 条
  • [1] FLUORESCENT-BASED LIFETIME MEASUREMENT THERMOMETER FOR USE AT SUBROOM TEMPERATURES (200-300 K)
    ANGHEL, F
    ILIESCU, C
    GRATTAN, KTV
    PALMER, AW
    ZHANG, ZY
    [J]. REVIEW OF SCIENTIFIC INSTRUMENTS, 1995, 66 (03) : 2611 - 2614
  • [2] Complexation of naphthylethanols with β-cyclodextrin
    Barros, TC
    Stefaniak, K
    Holzwarth, JF
    Bohne, C
    [J]. JOURNAL OF PHYSICAL CHEMISTRY A, 1998, 102 (28) : 5639 - 5651
  • [3] DEMONSTRATION THAT PHOSPHORESCENT 6-BROMO-2-NAPHTHYL SULFATE CAN BE USED TO PROBE HEME ACCESSIBILITY IN HEME-PROTEINS
    BAYLES, SW
    BECKHAM, S
    LEIDIG, PR
    MONTREM, A
    TAYLOR, ML
    WRIGHT, TM
    WU, Y
    SCHUH, MD
    [J]. PHOTOCHEMISTRY AND PHOTOBIOLOGY, 1991, 54 (02) : 175 - 181
  • [4] Brewster R., UNPUB
  • [5] THE USE OF EXOGENOUS FLUORESCENT-PROBES FOR TEMPERATURE-MEASUREMENTS IN SINGLE LIVING CELLS
    CHAPMAN, CF
    LIU, Y
    SONEK, GJ
    TROMBERG, BJ
    [J]. PHOTOCHEMISTRY AND PHOTOBIOLOGY, 1995, 62 (03) : 416 - 425
  • [6] A fluorescent molecular thermometer based on the nickel(II) high-spin/low-spin interconversion
    Engeser, M
    Fabbrizzi, L
    Licchelli, M
    Sacchi, D
    [J]. CHEMICAL COMMUNICATIONS, 1999, (13) : 1191 - 1192
  • [7] DELAYED FLUORESCENCE OPTICAL THERMOMETRY
    FISTER, JC
    RANK, D
    HARRIS, JM
    [J]. ANALYTICAL CHEMISTRY, 1995, 67 (23) : 4269 - 4275
  • [8] Solvent influences on the photophysics of naphthalene:: Fluorescence and triplet state properties in aqueous solutions and in cyclodextrin complexes
    Grabner, G
    Rechthaler, K
    Mayer, B
    Köhler, G
    Rotkiewicz, K
    [J]. JOURNAL OF PHYSICAL CHEMISTRY A, 2000, 104 (07) : 1365 - 1376
  • [9] INFRARED FLUORESCENCE DECAY-TIME TEMPERATURE SENSOR
    GRATTAN, KTV
    PALMER, AW
    [J]. REVIEW OF SCIENTIFIC INSTRUMENTS, 1985, 56 (09) : 1784 - 1787
  • [10] RUBY FLUORESCENCE WAVELENGTH DIVISION FIBEROPTIC TEMPERATURE SENSOR
    GRATTAN, KTV
    SELLI, RK
    PALMER, AW
    [J]. REVIEW OF SCIENTIFIC INSTRUMENTS, 1987, 58 (07) : 1231 - 1234