A diatropic ring current in a fluorofullerene trannulene

被引：27

作者：

Burley, GA ^{[1
]}

Fowler, PW

Soncini, A

Sandall, JPB

Taylor, R

机构：

[1] Univ Sussex, Sch Chem Phys & Environm Sci, Brighton BN1 9Q, E Sussex, England

[2] Univ Exeter, Dept Chem, Exeter EX4 4Q, Devon, England

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 24期

关键词：

D O I：

10.1039/b307514c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ipsocentric current-density maps for a fluorofullerene derivative, C60F15H3, modelling the addition pattern of the experimentally characterised C60F15[CBr(CO2Et)(2)](3) which contains an [18]trans-annulene system, reveal a diamagnetic ring current dominated by the contribution of the four HOMO electrons, as in a classical (4n + 2) aromatic annulene.

引用

页码：3042 / 3043

页数：2

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