The important role of tetrahedral Ti4+ sites in the phase transformation and photocatalytic activity of TiO2 nanocomposites

被引：177

作者：

Li, Gonghu ^{[1
]}

Dimitrijevic, Nada M. ^{[2
]}

Chen, Le ^{[1
]}

Nichols, Jamie M. ^{[1
]}

Rajh, Tijana ^{[2
]}

Gray, Kimberly A. ^{[1
]}

机构：

[1] Northwestern Univ, Inst Catalysis Energy Proc, Dept Civil & Environm Engn, Evanston, IL 60208 USA

[2] Argonne Natl Lab, Ctr Nanoscale Mat, Argonne, IL 60439 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 16期

关键词：

D O I：

10.1021/ja711118u

中图分类号：

O6 [化学];

学科分类号：

0703 [化学];

摘要：

Highly photoactive, tetrahedral Ti4+ sites can be created, other than in zeolite cavities and on silica substrate, in mixed-phase TiO2 nanocomposites. The tetrahedral Ti4+ species was shown to be an intermediate formed during the thermally driven phase transformation from anatase to futile.

引用

页码：5402 / +

页数：3

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