Red soil chemistry and mineralogy reflect uniform weathering environments in fluvial sediments, Taiwan

被引：29

作者：

Tsao, Tsung Ming ^{[2
]}

Chen, Yue Ming ^{[3
]}

Sheu, Hwo Shuenn ^{[4
]}

Zhuang, Shung Yao ^{[5
]}

Shao, Ping Hua ^{[6
]}

Chen, Hua Wen ^{[6
]}

Shea, Kai Shuan ^{[6
]}

Wang, Ming Kuang ^{[1
]}

Shau, Yen Horng ^{[7
]}

Chiang, Kai Yin ^{[1
]}

机构：

[1] Natl Taiwan Univ, Dept Agr Chem, Taipei 10617, Taiwan

[2] Natl Taiwan Univ, Chushan 55750, Nantou, Taiwan

[3] Acad Sinica, Biodivers Res Ctr, Taipei 11529, Taiwan

[4] Nat Synchrotron Radiat Res Ctr, Hsinchu 30076, Taiwan

[5] Chinese Acad Sci, State Key Lab Soil & Sustainable Agr, Inst Soil Sci, Nanjing 210008, Jiangsu, Peoples R China

[6] Minist Econ Affairs, Cent Geol Survey, Taipei 235, Taiwan

[7] Natl Sun Yat Sen Univ, Dept Marine Resource, Kaohsiung 425, Taiwan

来源：

JOURNAL OF SOILS AND SEDIMENTS | 2012年 / 12卷 / 07期

关键词：

Goethite; Hematite; Kaolinite; Laterite; Nanoparticle; Red soil; PARTICLE-SIZE; IRON-OXIDES; TERRACE; NANOPARTICLES;

D O I：

10.1007/s11368-012-0495-z

中图分类号：

X [环境科学、安全科学];

学科分类号：

083001 [环境科学];

摘要：

Information on the physicochemical properties, mineral species and micromorphology of lateritic soils and gravel soil layers in paleo-environmental soil profile is severely lacking. Red soil profile of the Taoyuan terrace was employed to demonstrate its different extents of lateritic weathering. The objectives of this study were to compare the physicochemical properties of lateritic soils and gravel soil layers and identify using conventional and synchrotron X-ray diffraction (XRD) analyses mineral species in nanoparticles separated by automated ultrafiltration device (AUD) apparatus. Soil samples were collected from paleo-environmental lateritic soils. Soil samples were examined using elemental analysis, conventional and synchrotron XRD analyses, high gradient magnetic separation, separation and collection of nanoparticles by AUD apparatus, and transmission electron microscopy (TEM). The soil pH, redness index, quantities of free Al- and Fe-oxides (Al-d and Fe-d), and clay content of lateritic soils are higher than those of gravel soil layers. Illite, kaolinite, gibbsite, quartz, goethite, and hematite were identified in clay fractions and nanoparticles by conventional and synchrotron XRD analyses. TEM images show presence of hematite nanoparticles on the surface coating of kaolinite nanoparticles and aggregated hematite nanoparticles overlapping the edge of a kaolinite flake in a size range of 4-7 nm. Synchrotron XRD techniques are more straightforward and powerful than conventional XRD with random powder methods for identifying nanoparticles in red soils, particularly for illite, kaolinite, goethite, and hematite nanoparticles. According to chemical compositions of clay fractions and red soil features in the Taoyuan terrace, these red soils can be taken as lateritic red earths or red earths. This work suggests that physicochemical properties, mineral species, and micromorphology of red soil at all depths can shed light on the extent of paleo-environmental lateritic weathering.

引用

页码：1054 / 1065

页数：12

共 57 条

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